Intermolecular hydrogen transfer in unsaturated hydrocarbons induced by dimeric titanocene

…, L Petrusová, H Antropiusová, V Hanuš…

Index: Mach, Karel; Petrusova, Lidmila; Antropiusova, Helena; Hanus, Vladimir; Turecek, Frantisek; Sedmera, Petr Collection of Czechoslovak Chemical Communications, 1983 , vol. 48, # 10 p. 2924 - 2936

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Citation Number: 5

Abstract

Abstract μ-(η 5: η 5-Fulvalene)-di-μ-hydrido-bis (η 5-cyclopentadienyltitanium) and μ-(η 5: η 5-fulvalene)-μ-chloro-μ-hydrido-bis (cyclopentadienyltitanium) form a thermally stable complex which catalyzes the intermolecular hydrogen transfer in unsaturated hydrocarbons, in addition to isomerizations and cyclizations. Cyclic hydrocarbons disproportionate under catalysis to saturated and aromatic hydrocarbons, while linear olefins yield predominantly ...