Journal of the American Chemical Society

Marcus theory of a perpendicular effect on. alpha. for hydride transfer between NAD+ analogs

MM Kreevoy, ISH Lee

Index: Kreevoy, Maurice M.; Lee, In-Sook Han Journal of the American Chemical Society, 1984 , vol. 106, # 9 p. 2550 - 2553

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Citation Number: 111

Abstract

Abstract: The Brernsted a (I d (ln ku)/d (ln KO)) for an atom-or group-transfer reaction depends on the location of the substitution and the tightness of the transition state (7) as well as the resemblence of the transition state to reactants and products. Within Marcus theory, 7 can be related to rates of symmetrical reactions. These ideas have been successfully applied to hydride transfer between NAD'analogues. A series of 1-benzyl-3- ...