Chemistry of acetylenic ethers LII acetylenic tert. Butyl ethers and some other acetylenic ethers with branched alkyl groups: Some remarks concerning the preparation …

JJ Van Daalen, A Kraak…

Index: van Daalen,J.J. et al. Recueil des Travaux Chimiques des Pays-Bas, 1961 , vol. 80, p. 810 - 818

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Citation Number: 23

Abstract

Abstract Tert. butoxyethyne IV and some 1-tert. butoxy-1-alkynes V have been prepared as outlined in the scheme below. The elimination of HBr from 2-bromo-1, 2-unsaturated ethers such as III and VI by means of sodium amide in liquid ammonia gives much better yields of acetylenic ethers than the procedure using KOH. Some examples of this modification of a much used method for the preparation of acetylenic ethers are given. In the case of ...