A general olefin synthesis

E Wenkert, TW Ferreira

Index: Wenkert, Ernest; Ferreira, Tamis W. Journal of the Chemical Society, Chemical Communications, 1982 , # 15 p. 840 - 841

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Citation Number: 34

Abstract

The reaction between secondary Grignard reagents and alkylthioarenes or alkylthioalkenes in the presence of 1: 1 nickel dichloride–triphenylphosphine causing the substitution of alkylthio-groups by hydrogen atoms, the nickel (0)-induced replacement of alkylthio-groups of the aforementioned sulphides by alkyl or aryl functions, and the observation of regiocontrol in the catalysed reactions of Grignard reagents with unsymmetrical 1, 1-bis ( ...

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