Tetrahedron: Asymmetry

New chiral synthons from the microbial oxidation of bromonaphthalenes

T Hudlicky, MAA Endoma, G Butora

Index: Hudlicky, Tomas; Endoma, Mary Ann A.; Butora, Gabor Tetrahedron Asymmetry, 1996 , vol. 7, # 1 p. 61 - 68

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Citation Number: 18

Abstract

1-Bromo-and 2-bromonaphthalene were subjected to bio-oxidation with whole cells of Pseudomonas putida NCIB 9816-11. The major metabolites were isolated and spectroscopically characterized as (+)-cis-(1R, 2S)-Dihydroxy-1, 2-dihydro-8- bromonaphthalene 1,(+)-cis-(1R, 2S-Dihydroxy-1, 2-dihydro-5-bromonaphthalene 2 from 1- bromo-naphthalene and (+)-cis-(1R, 2S)-Dihydroxy-1, 2-dihydro-7-bromonaphthalene 8 ...

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