Synthesis, characterization and crystal structures of nickel (II), palladium (II) and copper (II) complexes with 2-furaldehyde-4-phenylthiosemicarbazone

DC Ilies, E Pahontu, S Shova, A Gulea, T Rosu

Index: Ilies, Diana-Carolina; Pahontu, Elena; Shova, Sergiu; Gulea, Aurelian; Rosu, Tudor Polyhedron, 2013 , vol. 51, # 1 p. 307 - 315

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Citation Number: 4

Abstract

2-Furaldehyde-4-phenylthiosemicarbazone (HL) and its nickel (II), palladium (II) and copper (II) complexes:[Pd (L) 2](1),[Ni (L) 2](2),[Cu2 (L) 2 (Et3N) 2 (H2O) 4](SO4)(3),[Cu2 (L) 2 (Et3N) 2 (H2O) 4](NO3) 2 (4),[Cu (L) 2 (H2O) 2](5),[Cu (L)(OAc)(H2O)](6) were synthesized and characterized. The ligand has been characterized by elemental analyses, IR, electronic, 1H NMR and 13C NMR spectroscopy. The bidentate nature of the ligand is evident from ...