Catalytic Conversions in Water. Part 23: Steric Effects and Increased Substrate Scope in the Palladium??Neocuproine Catalyzed Aerobic Oxidation of Alcohols in …

…, M Hoogenraad, G Verspui, RA Sheldon

Index: Ten Brink, Gerd-Jan; Arends, Isabel W. C. E.; Hoogenraad, Marcel; Verspui, Goeran; Sheldon, Roger A. Advanced Synthesis and Catalysis, 2003 , vol. 345, # 12 p. 1341 - 1352

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Citation Number: 88

Abstract

Abstract The steric influence of substituents on the 2-and 9-positions of phenanthroline in the (2, 9-R 2-1, 10-phenanthroline) palladium (II)-catalyzed aerobic oxidation of 2-hexanol was investigated by means of high throughput experimentation.(Neocuproine) Pd (OAc) 2 (R [DOUBLE BOND] CH 3) was found to be a highly active catalyst for alcohol oxidation in 1: 1 water/DMSO mixtures. The catalyst is unique in that it tolerates water, polar co-solvents ...

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