Synthesis and molecular recognition of pyrenophanes with polycationic or amphiphilic functionalities: Artificial plate-shaped cavitant incorporating arenes and …

…, Y Mawatari, H Teraoka, K Fujimoto…

Index: Abe, Hajime; Mawatari, Yosuke; Teraoka, Haruna; Fujimoto, Kazuhisa; Inouye, Masahiko Journal of Organic Chemistry, 2004 , vol. 69, # 2 p. 495 - 504

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Citation Number: 75

Abstract

Water-soluble pyrenophanes possessing polycationic or amphiphilic side chains have been developed as synthetic host molecules to investigate hydrophobic and/or π-stacking interactions. By utilizing ω-acetalic alkyl side chains to retain solubility and versatility, water- soluble macrocyclic pyrenophanes could be easily obtained by Stille coupling, followed by conversion of the acetal groups to hydrophilic substituents. Among the pyrenophanes ...

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