Novel synthesis of sulfonimidoyl halides and sulfonimidates from N-silylated sulfonamides and dihalophosphoranes

AK Roy

Index: Roy, Aroop K. Journal of the American Chemical Society, 1993 , vol. 115, # 7 p. 2598 - 2601

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Citation Number: 20

Abstract

Abstract: In the past, general methods for the preparation of sulfonimidoyl chlorides have involved oxidation of sulfur-(IV) compounds with various oxidizing agents. For the purpose of studying the thermal decomposition of suitably substituted sulfonimidates to sulfur-nitrogen based polymeric materials, a simple method was developed for the synthesis of sulfonimidoyl halides from readily available sulfur (V1) starting materials. Unsubstituted ...