Syntheses of Novel 4-Polfluoroalkyl-Substituted 5, 6-Oligomethylene Pyrimidines

…, MI Kodess, J Stelten, I Loop, E Lork, KI Pashkevich…

Index: Sevenard; Khomutov; Koryakova; Sattarova; Kodess; Stelten; Loop; Lork; Pashkevich; Roschenthaler Synthesis, 2000 , # 12 p. 1738 - 1748

Full Text: HTML

Citation Number: 27

Abstract

Abstract: 2-Acylcycloalkanones having polyfluoroalkyl groups react with guanidine, urea, thiourea, methylisothiourea, benzamidine, guanylthiourea, dicyanodiamide, and trifluoroacetylurea by Lewisacid catalysis to form the corresponding 5, 6-oligomethylene pyrimidines. A decrease in the yields along with increase of polyflyoroalkyl substituent length in the molecule of the starting 1, 3-diketone was observed in the case of reagents ...

Related Articles:

More Articles...