Conversion of N-substituted N-sulfonylhydrazines into hydroperoxides-a new synthetic route to hydroperoxides via hydroperoxydeamination

L Collazo, FS Guziec Jr, WX Hu, A Munoz…

Index: Collazo, Luis; Guziec, Frank S.; Hu, Wei-Xiao; Munoz, Antonio; Wei, Dongchu; Alvarado, Migdalia Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6169 - 6170

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Citation Number: 7

Abstract

Standard approaches to the synthesis of organic hy- droperoxides are often severely limited in scope.2 These limitations can involve the inherent selectivity associated with direct radical oxygenations, the high reactivity of intermediate organometallic reagents, or the steric and electronic requirements in a displacement using hydrogen peroxide or a peroxide derivative.3 Alternate routes to hydroperoxides involving readily available starting ma- terials and mild reaction ...

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