First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds

…, LV Afanas' eva, SV Vitt, PV Petrovskii

Index: Akhrem, Irena S.; Afanas'eva, Lyudmila V.; Vitt, Sergei V.; Petrovskii, Pavel V. Mendeleev Communications, 2002 , vol. 12, # 5 p. 180 - 182

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Citation Number: 5

Abstract

The carbonylation of C6–C10n-alkanes with CO in the presence of CBr4· 2AlBr3 at–40° C and 1 atm CO leads to the products of non-destructive carbonylation, ie, the esters of tertiary carboxylic acids, R1C (Me) 2COOR and R2 (Et) C (Me) COOR, after the workup of reaction mixtures with ROH.

Enolates d'esters: V. Preparation des analogues lithiens des reactifs de reformatsky a partir des esters α, α-dichlores et α-monohalogenes. Reactivite

[Villieras,J. et al. Journal of Organometallic Chemistry, 1975 , vol. 102, p. 129 - 140]

First examples of the selective carbonylation of C6–C10 linear alkanes to tertiary carbonyl-containing compounds

Abstract

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