Selective Formation of Propargylsilanes and Allenylsilanes and Their Reactions with Aldehydes for the Preparation of Homopropargylic and Allenic Alcohols

S Kobayashi, K Nishio

Index: Kobayashi, Shu; Nishio, Koichi Journal of the American Chemical Society, 1995 , vol. 117, # 23 p. 6392 - 6393

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Citation Number: 85

Abstract

Acetylene and allene compounds and their chemistry have attracted much attention during the past two decades.'Regioselective reactions of propargyl and allenyl organometallics provide a potentially useful route for the synthesis of these compounds; however, these organometallics often exist as an equilibrium mixture, la and few examples for the selective synthesis of these unstable intermediates are kn0wn.~ 3~ In this paper, we report the ...