High Temperature, Vapor Phase Reactions of Some Fluorocarbon Derivatives with Oxidizing Agents

WA Severson, TJ Brice

Index: Severson; Brice Journal of the American Chemical Society, 1958 , vol. 80, p. 2313,2316

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Citation Number: 8

Abstract

Vapor phase, high temperature (450-650") reactions of perfluoroalkanesulfonyl fluorides or fluorocarbon derivatives having the structures RrCFzX (X= H, C1, Br, I) with oxidizing agents, principally SO2, were carried out. SO2 gave, in several cases, good yields of perfluoroalkanecarboxylic acid fluorides; the products usually were isolated as the acids because of hydrolysis and separation problems. RfCFzH compounds require a sensitizing ...