Synthesis and Reaction of Novel Sulfur Containing Heterocyclic Systems

W Ando, N Tokitoh, Y Kabe

Index: Ando, Wataru; Tokitoh, Norihiro; Kabe, Yoshio Phosphorus, Sulfur and Silicon and the Related Elements, 1991 , vol. 58, # 1-4 p. 179 - 205

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Citation Number: 11

Abstract

Abstract The strained alkylidene episulfides were synthesized by carbene and alkylidene carbene additions to thiocarbonyl compounds. Thermal, photochemical, and acid catalyzed reactions have been extensively investigated, and and the transition metal-promoted reaction results in the first isolation of thioallyl iron tricarbonyl complex. Germylene and zirconocene also reacted with thioketene to give metallic analogue of alkylidene ...

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