Palladium-catalyzed carbonylative coupling of vinyl triflates with organostannanes. A total synthesis of (.+-.)-. DELTA. 9 (12)-capnellene

GT Crisp, WJ Scott, JK Stille

Index: Crisp,G.T.; Scott,W.J.; Stille,J.K. Journal of the American Chemical Society, 1984 , vol. 106, p. 7500

Full Text: HTML

Citation Number: 176

Abstract

Abstract: The palladium-catalyzed carbonylative coupling of vinyl triflates with alkyl-, vinyl-, allyl-, and arylstannanes gives good yields of the cross-coupled ketone products. Regioselectively formed vinyl triflates can be used to produce divinyl ketones as regioisomerically pure compounds. The E and Z geometry of the vinylstannane is maintained during the coupling reaction. This methodology was applied to a total ...

Related Articles:

Cathodic addition of benzylidyne trichloride to ketones and aldehydes.

[Steiniger, Michael; Schaefer, Hans J. Bulletin of the Chemical Society of Japan, 1988 , vol. 61, # 1 p. 125 - 132]

1, 2??Addition of α, α, α??Trichlorotoluene to Ketones via a Mg Barbier Reaction in DMF: New Route to Cycloalk??1??en??1??yl and Alk??1??en??1??yl Phenyl Ketones

[Aaziz, Akima; Oudeyer, Sylvain; Leonel, Eric; Paugam, Jean Paul; Nedelec, Jean-Yves Synthetic Communications, 2007 , vol. 37, # 7 p. 1147 - 1154]

More Articles...