Tetrahedron letters

Copper (1) catalysed aromatic nucleophilic substitution: a mechanistic and synthetic comparison with the SRN1 reaction

WR Bowman, H Heaney, PHG Smith

Index: Bowman, W. Russel; Heaney, Harry; Smith, Philip H. G. Tetrahedron Letters, 1984 , vol. 25, # 50 p. 5821 - 5824

Full Text: HTML

Citation Number: 72

Abstract

Abstract Evidence is provided to support a mechanism for Cu (1) catalysed aromatic nucleophilic substitution via inner-sphere electron-transfer and a Cu (111) intermediate, and to show the synthetic potential for Cu (1) catalysis relative to the S RN 1 reaction.

Related Articles:

Magnesium-induced copper-catalyzed synthesis of unsymmetrical diaryl chalcogenide compounds from aryl iodide via cleavage of the Se-Se or SS bond

[Taniguchi, Nobukazu; Onami, Tetsuo Journal of Organic Chemistry, 2004 , vol. 69, # 3 p. 915 - 920]

A convenient s rn 1 synthesis of aromatic nitriles from diazonium salts via diazosulfides

[Petrillo, Giovanni; Novi, Marino; Garbarino, Giacomo; Dell'erba, Carlo Tetrahedron, 1987 , vol. 43, # 20 p. 4625 - 4634]

A convenient s rn 1 synthesis of aromatic nitriles from diazonium salts via diazosulfides

[Tetrahedron, , vol. 43, # 20 p. 4625 - 4634]

A mild and efficient SRN1 approach to diaryl sulfides from arenediazonium tetrafluoroborates

[Petrillo, Giovanni; Novi, Marino; Garbarino, Giacomo; Dell'Erba, Carlo Tetrahedron, 1986 , vol. 42, # 14 p. 4007 - 4016]

A mild and efficient SRN1 approach to diaryl sulfides from arenediazonium tetrafluoroborates

[Petrillo, Giovanni; Novi, Marino; Garbarino, Giacomo; Dell'Erba, Carlo Tetrahedron, 1986 , vol. 42, # 14 p. 4007 - 4016]

More Articles...