The Journal of Organic Chemistry

Mechanism of hydrolysis of aryl vinyl selenides. Selenium-stabilized carbonium ions

RA McClelland, M Leung

Index: McClelland, Robert M.; Leung, Michael Journal of Organic Chemistry, 1980 , vol. 45, # 1 p. 187 - 189

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Citation Number: 21

Abstract

C15H2002, 232.146). Selenium-Stabilized Carbonium Ions 3-Methoxy-5, 6, 9, 10, 11, 12- hexahydro-8 (7H)-benzocyclo-decenone (4b) was prepared in 38% yield from 3b by the earlier procedures2 using KH and HMPT at room temperature for 40 min: IR (neat) 2920, 2850, 1698, 1605, 1570, 1500, 1480, 1450, 1365, 1295, 1245, 1230, 1212, 1180, 1140, 1100, 1040, 1000, 995, 970, 930,910,880, 860, 850, 800, 750, 700 cm-'; NMR (CC14) 6 ...

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