Catalytic oxidation of alkenes with a surface-bound metalloporphyrin-peptide conjugate

GR Geier, T Sasaki

Index: Geier III, G. Richard; Sasaki, Tomikazu Tetrahedron, 1999 , vol. 55, # 7 p. 1859 - 1870

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Citation Number: 47

Abstract

A novel surface-bound metalloporphyrin-peptide conjugate was prepared and used to catalytically oxidize alkenes in the presence of iodosylbenzene. The catalyst was found to oxidize a number of alkene substrates in good yield under a variety of reaction conditions. Comparison to control experiments using surface-bound Mn (III) tetraphenylporphyrin showed differences in oxidation yields and ratios of oxidized products. Substrate ...