Reactions of bis (bistrifluoromethylamino-oxy)-mercury (II) and NN-bis (trifluoromethyl) nitroxide with thiocarbonyl compounds

…, RF Browne, RN Haszeldine, JS Varley

Index: Booth, B. L.; Browne, R. F.; Haszeldine, R. N.; Varley, J. S. Journal of Fluorine Chemistry, 1984 , vol. 24, p. 485 - 502

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Citation Number: 4

Abstract

Abstract Thiobenzophenone, 9-thiocarbonylfluorene and carbonyl sulphide react with the mercurial, Hg [ON (CF 3) 2] 2, to form HgS and the compounds Ph 2 C [ON (CF 3) 2] 2,(C 6 H 4) 2 C [ON (CF 3) 2] 2 and [(CF 3) 2 NO] 2 CO respectively. The last compound is also formed as the major product on mixing the mercurial with carbon disulphide. With thiophosgene, reaction occurs to form HgCl 2 and a mixture of the compounds (CF 3) 2 ...

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