Preparation and properties of tristrifluoromethylhydrazyl compounds

RC Dobbie, HJ Emeléus

Index: Dobbie,R.C.; Emeleus,H.J. Journal of the Chemical Society [Section] A: Inorganic, Physical, Theoretical, 1966 , p. 933 - 935

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Citation Number: 4

Abstract

N-Chlorobistrifluoromethylamine reacts with cyanogen chloride on irradiation to give bistrifluoromethylaminocarbylamine chloride,(CF3) 2N· N: CCl2. Fluorination of the carbylamine chloride with sodium fluoride gives (C3F8N2) 2; a structure for the dimer is proposed. Reaction with mercuric fluoride produces a crystalline mercurial,[(CF3) 2N· N (CF3)] 2Hg. Perfluorohexamethyltetrazine, N-bromotristrifluoromethylhydrazine, ...

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