A Chlorinative Ring Expansion. The Reaction of t-Butyl Hypochlorite and 1-Vinylcycloalkanols1

CR Johnson, CJ Cheer…

Index: Johnson,C.R. et al. Journal of Organic Chemistry, 1964 , vol. 29, p. 3320 - 3323

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Citation Number: 26

Abstract

The homologation of alicyclic systems has been effected by a variety of cati0ni. c methods3; most notable are the Demjanov* a, c and Tiff eneau-Demjano~~~~~ reactions, the acid- catalyzed dehydration of alcohol^,^ reactions with diazo compound~,~, 5 the solvolysis of sulfonates,'j and the anodic oxidation of P-hydroxy acids.'In all these systems, one point of similarity is immediately obvious; all involve the generation of carbonium ion character on ...