Synthesis, crystal structure, and chromotropic properties of mixed-ligand Nickel (II) complexes with 1, 3-diketonate and PN bidentate Ligands

M Arakawa, N Suzuki, S Kishi, M Hasegawa…

Index: Arakawa, Machiko; Suzuki, Noriyuki; Kishi, Shinobu; Hasegawa, Miki; Satoh, Keiichi; Horn, Ernst; Fukuda, Yutaka Bulletin of the Chemical Society of Japan, 2008 , vol. 81, # 1 p. 127 - 135

Full Text: HTML

Citation Number: 10

Abstract

Mixed-ligand nickel (II) complexes Ni (acac)(dmap) X,[Ni (acac)(dmap)] BPh 4 (1),[Ni (acac)(dmap)] BF 4 (2), and [Ni (acac)(dmap) NO 3](3)(where acac= acetylacetonate and dmap= 1-dimethylamino-2-diphenylphosphinoethane) have been obtained for the first time and their X-ray single-crystal structures have also been determined. This series of complexes show different structures, hence colors, in the solid state depending on the ...