Reaction of P (III) chlorides with aldehydes: III. Reaction of primary intermediates with oxidants and chlorinating agents

MB Gazizov, RA Khairullin, RF Karimova

Index: Gazizov; Khairullin; Karimova Russian Journal of General Chemistry, 2014 , vol. 84, # 1 p. 75 - 81 Zh. Obshch. Khim., 2014 , vol. 84, # 1 p. 79 - 85,7

Full Text: HTML

Citation Number: 0

Abstract

Abstract Primary intermediates of P (III) chlorides reaction with aldehydes have been converted into the corresponding phosphates by treating with oxidants: dimethylsulfoxide and tert-butyl hypochlorite. In reactions of the intermediates with chlorinating agents (PCl 5 and Cl 2) the oxidation products are formed (due to the ligand exchange at quasiphosphonium center) along with the expected P (IV) acid chlorides.