Dehydration of Phenylboronic Acid to Boroxine Catalyzed by Au n Nanoclusters with Atom Packing Core–Shell Structure

P Huang, Z Jiang, G Chen, Y Zhu…

Index: Huang, Ping; Jiang, Zhi; Chen, Guoxiang; Zhu, Yan; Sun, Yuhan Journal of Nanoscience and Nanotechnology, 2013 , vol. 13, # 7 p. 5088 - 5092

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Abstract

Atomically precise Au n nanoclusters (n= number of gold atom in cluster) ideally composed of an exact number of gold atoms have unique core–shell structure and non-metallic electronic properties. The extremely small size of Au25 and Au38 nanoclusters induces a large energy gap in their electronic structures, which gives rise to unprecedented catalytic activity in some chemical reactions. Here we report dehydration of phenylboronic acid to ...

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