Tetrahedron letters

A novel approach to α-keto acid derivatives via palladium-catalyzed arylation and vinylation of methyl α-methoxyacrylate

S Cacchi, PG Ciattini, E Morera, G Ortar

Index: Cacchi, Sandro; Ciattini, Pier Giuseppe; Morera, Enrico; Ortar, Giorgio Tetrahedron Letters, 1987 , vol. 28, # 26 p. 3039 - 3042

Full Text: HTML

Citation Number: 33

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Methyl α-methoxyacrylate reacts stereoselectively with aryl iodides and vinyl triflates under palladium catalysis to give enol ethers of arylpyruvates and of β,γ-unsaturated α-keto esters in good to moderate yields. ... By the palladium catalysis methyl α-methoxyacrylate reacts with aryl iodides ...

Related Articles:

Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E-and Z-2-alkoxy-and 2-aryloxy-2-alkenoates

[Seneci, Pierfausto; Leger, Isabelle; Souchet, Michel; Nadler, Guy Tetrahedron, 1997 , vol. 53, # 50 p. 17097 - 17114]

Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E-and Z-2-alkoxy-and 2-aryloxy-2-alkenoates

[Seneci, Pierfausto; Leger, Isabelle; Souchet, Michel; Nadler, Guy Tetrahedron, 1997 , vol. 53, # 50 p. 17097 - 17114]

Total synthesis of cystothiazoles A and C

[Gompper, Rudolf; Vogt, Hans-Hubert Chemische Berichte, 1981 , vol. 114, # 8 p. 2866 - 2883]

Stereoselective addition of 2-aminothiophenol to α-alkoxycinnamic acid derivatives—alternative synthesis of (±)-diltiazem—

[Miyata, Okiko; Shinada, Tetsuro; Naito, Takeaki; Ninomiya, Ichiya; Date, Tadamasa; Okamura, Kimio Tetrahedron, 1993 , vol. 49, # 36 p. 8119 - 8128]

Stereoselective alkenylation of aldehydes with phosphorus carbanions: Preparation of E-and Z-2-alkoxy-and 2-aryloxy-2-alkenoates

[Seneci, Pierfausto; Leger, Isabelle; Souchet, Michel; Nadler, Guy Tetrahedron, 1997 , vol. 53, # 50 p. 17097 - 17114]

More Articles...