The Journal of Organic Chemistry

Ynamines from 1, 1-difluoro-2-aryl and 2-alkylethylenes

DR Strobach

Index: Strobach,D.R. Journal of Organic Chemistry, 1971 , vol. 36, p. 1438 - 1440

Full Text: HTML

Citation Number: 11

Abstract

(0.248 mol) of 4-cyclooctenone1B and 73 g (0.27 mol) of methyl- ene iodide was added in one portion. The mixture was refluxed for 2 days, after which glpc analysis of the ether solution indi- cated that the reaction had only gone to a small extent (ca. 30%). Another 18 g of the zinc-copper couple was added to the mixture and this was followed by another 73 g (0.27 mol) of methylene iodide. The mixture was then refluxed for another 2 days. The mixture ...

Related Articles:

Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl) trimethylsilane and triphenylphosphine

[Wang, Fei; Li, Lingchun; Ni, Chuanfa; Hu, Jinbo Beilstein Journal of Organic Chemistry, 2014 , vol. 10, p. 344 - 351]

The use of methyl 2, 2-difluoro-2-(fluorosulfonyl) acetate as the difluorocarbene source to generate an in situ source of difluoromethylene triphenylphosphonium ylide

[Thomoson, Charles S.; Martinez, Henry; Dolbier Jr., William R. Journal of Fluorine Chemistry, 2013 , vol. 150, p. 53 - 59]

Organocuprate-induced substitution of the enol oxygen moiety in 2, 2-difluoro enol phosphates with allyl halides: a novel route to gem-diffluoroolefins from …

[Ishihara, Takashi; Yamana, Masayuki; Ando, Teiichi Tetrahedron Letters, 1983 , vol. 24, # 50 p. 5657 - 5660]

Réactivité des diènes et styrènes fluorés obtenus par réaction de couplage au palladium

[Tellier, Frederique; Sauvetre, Raymond; Normant, Jean F.; Dromzee, Yves; Jeannin, Yves Journal of Organometallic Chemistry, 1987 , vol. 331, # 3 p. 281 - 298]

Novel 2, 2-difluorovinylzirconocene: A facile synthesis of monosubstituted gem-difluoroolefinsvia its cross-coupling reaction

[Ichikawa, Junji; Fujiwara, Masaki; Nawata, Hideyuki; Okauchi, Tatsuo; Minami, Toru Tetrahedron Letters, 1996 , vol. 37, # 48 p. 8799 - 8802]

More Articles...