Tetrahedron Letters

α-Phenylselenenylation of aldehydes and ketones with diphenyl diselenide mediated by KF/Al 2 O 3

M Nazari, B Movassagh

Index: Nazari, Mohammad; Movassagh, Barahman Tetrahedron Letters, 2009 , vol. 50, # 13 p. 1453 - 1455

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Citation Number: 17

Abstract

The utility of KF/Al2O3 for the synthesis of α-phenylseleno aldehydes and ketones from the corresponding aldehydes or ketones and diphenyl diselenide has been investigated. Simple stirring of a mixture of aldehyde or ketone and diphenyl diselenide in the presence of KF/Al2O3 at room temperature selectively produces the corresponding α-phenylseleno aldehyde or ketone in good to excellent yields.

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