Australian Journal of Chemistry

Reaction of diarylcarbinols and diarylolefins with thionyl chloride: A synthesis of 3-arylbenzothiophens

H Blatt, JJ Brophy, LJ Colman, WJ Tairych

Index: Blatt,H. et al. Australian Journal of Chemistry, 1976 , vol. 29, p. 883 - 890

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Citation Number: 5

Abstract

Abstract Treatment of 1, l-diphenylalkan-1-ols and 1, l-diphenylalk-l-enes with thionyl chloride gives 3-phenyl-benzo [b] thiophens in approximately 50% yields. Also formed in these reactions are 2-chloro-1, l-diphenylalk-l-enes and 1, 2-dichloro-1, l-diphenylalkanes. 5, 6-Dihydrobenzo [b] naphtho [l, 2-dlthiophen was formed from l-phenyl-3, 4- dihydronaphthalene under these conditions.

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