Photoinduced oxygen transfer from nitrogen dioxide to ethylene in the vicinity of the nitrogen dioxide dissociation threshold: a laser photochemical study on reactant …

DJ Fitzmaurice, H Frei

Index: Fitzmaurice, Donald J.; Frei, Heinz Journal of Physical Chemistry, 1992 , vol. 96, # 25 p. 10308 - 10315

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Citation Number: 27

Abstract

The wavelength dependence of the photochemistry of C 2 QN 0 2 and C2D,-N02 pairs, isolated in did Ar, in the range 555-355 nm is reported. Continuous-wave and pulsed dye lasers were used to excite the reactants, and the products were monitored by FT infrared spectroscopy. Acetaldehyde, ethylene oxide, NO, and ethyl nitrite radical were the products observed at wavelengths longer than the 398-nm dissociation threshold of NO2. D isotope ...