Chemical physics letters

Thermochemical study of the liquid phase equilibrium reaction of dihalomethanes by NMR spectroscopy

JZ Dávalos, AF Lago, T Baer

Index: Davalos; Lago; Baer, Tomas Chemical Physics Letters, 2005 , vol. 409, # 4-6 p. 230 - 234

Full Text: HTML

Citation Number: 6

Abstract

The liquid phase equilibrium reaction of dihalomethanes (2CH2BrI⇄ CH2Br2+ CH2I2) has been investigated by NMR spectroscopy, as a function of the temperature and initial concentration of the reactants. The equilibrium constants have been experimentally determined for this reaction from the profile of the NMR spectra. Heat capacity measurements were carried out in the temperature range from 293.15 to 353.15 K by ...

Related Articles:

Determination, synthesis and survey of iodinated trihalomethanes in water treatment processes

[Cancho, Beatriz; Ventura, Francesc; Galceran, Materesa; Diaz, Alfredo; Ricart, Susagna Water Research, 2000 , vol. 34, # 13 p. 3380 - 3390]

High-field NMR determination of magnetic susceptibility tensors and angular correlation factors of halomethanes

[Bothner-By, A. A.; Dadok, J.; Mishra, P. K.; Zijl, P. C. M. Van Journal of the American Chemical Society, 1987 , vol. 109, # 14 p. 4180 - 4184]

Transformation of aldehydes into (E)-1-alkenylsilanes and (E)-1-alkenylboronic esters with a catalytic amount of a chromium salt

[Takai, Kazuhiko; Kunisada, Yuji; Tachibana, Yukiko; Yamaji, Nana; Nakatani, Emi Bulletin of the Chemical Society of Japan, 2004 , vol. 77, # 8 p. 1581 - 1586]

Studies on the synthesis of heterocyclic compounds. XVI. Cleavage of 1, 3??benzodioxoles and??benzoxathioles by sodium iodide??acyl chloride

[Corda, Luciana; Fadda, Anna Maria; Maccioni, Antonio; Maccioni, Anna Maria; Podda, Gianni Journal of Heterocyclic Chemistry, 1988 , vol. 25, p. 311 - 314]

Photoproduct Characterization and Dynamics in the 248 nm Photolysis of CH3I Thin Films on Ag (111)

[Coon, S. R.; Myli, K. B.; Grassian, V. H. Journal of Physical Chemistry, 1995 , vol. 99, # 44 p. 16416 - 16424]

More Articles...