Revisiting the thermal decomposition of five ortho-substituted phenyl azides by calorimetric techniques

P Cardillo, L Gigante, A Lunghi, P Zanirato

Index: Cardillo, Paolo; Gigante, Lucia; Lunghi, Angelo; Zanirato, Paolo Journal of Thermal Analysis and Calorimetry, 2010 , vol. 100, # 1 p. 191 - 198

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Citation Number: 12

Abstract

Abstract The thermal decomposition (TD) of 2-azidophenylmethanol (1), 2- azidobenzenecarbaldehyde (2), 1-(2-azidophenyl)-1-ethanone (3),(2-azidophenyl)(phenyl) methanone (4) and 1-azido-2-nitrobenzene (5) was analysed by DSC, TG and C80 calorimetric techniques under both oxidative and non-oxidative conditions. The TD of these azides in solution is well known to give the corresponding benzoxazoles, generally in ...

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