An efficient and versatile generation of o-xylylenes by fluoride anion induced 1, 4 elimination of o-(. alpha.-trimethylsilylalkyl) benzyltrimethylammonium halides

Y Ito, M Nakatsuka, T Saegusa

Index: Ito,Y.; Nakatsuka,M.; Saegusa,T. Journal of the American Chemical Society, 1980 , vol. 102, p. 863

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Citation Number: 83

Abstract

Cycloaddition of olefins to o-xylylenes provides a convenient synthetic method for the preparation of tetrahydronaphthalene derivatives. The o-xylylene moiety is generated in situ by the metal inducedl or thermal2 1, 4 elimination reactions of the corresponding o-xylylene derivatives such as o-xylylene dihalides and o-methylbenzyltrimethylammonium hydroxides. Intramolecular cyc! oaddition of o-xylylenes generated by electrocyclic ring opening of ...

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