Reaction of aminosulfenates and dialkyl sulfoxylates with methyl trifluoromethanesulfonate and sodium iodide: NMR spectroscopic studies

…, B Bujnicki, E Wenschuh, U Kühne

Index: Mikolajczyk, Marian; Kielbasinski, Piotr; Bujnicki, Bogdan; Wenschuh, Eberhard; Kuehne, Ulrich Phosphorus and Sulfur and the Related Elements, 1985 , vol. 25, p. 85 - 90

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Citation Number: 4

Abstract

Abstract Treatment of aminosulfenates and dialkyl sulfoxylates with methyl trifluoromethanesulfonate-sodium iodide reagent proved to be a convenient method for synthesis of sulfinamides and sulfinates, respectively. It was demonstrated by means of low temperature 1H-NMR spectroscopy that methylation of morpholine-and piperidinesulfenates by TfOMe occurs at the sulfur atom leading to the corresponding ...