Electrochemical reduction of 1-iodo-5-decyne and 1-bromo-5-decyne at mercury cathodes in dimethylformamide

…, JA Cleary, DM La Perriere, DG Peters

Index: Shao, Rui-lian; Cleary, James A.; Perriere, Daniel M. La; Peters, Dennis G. Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3289 - 3294

Full Text: HTML

Citation Number: 17

Abstract

Pulse polarograms for 1-iodo-5-decyne in dimethylformamide containing tetramethylammonium perchlorate exhibit two waves. At potentials corresponding to the first wave, electrolysis of 1-iodo-5-decyne at mercury results in 5-decynyl radicals that (i) adsorb onto and interact with the mercury electrode to give 5-decynylmercury radicals which disproportionate into di-bdecynylmercury or (ii) cyclize and then accept a hydrogen atom ...

Related Articles:

Catalytic reduction and intramolecular cyclization of haloalkynes in the presence of nickel (I) salen electrogenerated at carbon cathodes in dimethylformamide

[Ischay, Michael A.; Mubarak, Muhammad S.; Peters, Dennis G. Journal of Organic Chemistry, 2006 , vol. 71, # 2 p. 623 - 628]

Reactions of some alkynyl halides with Samarium (II) iodide

[Zhou, Zhihong; Larouche, Denis; Bennett, Sharon M. Tetrahedron, 1995 , vol. 51, # 43 p. 11623 - 11644]

Cyclization of acetylenic alkyllithiums

[Bailey, William F.; Ovaska, Timo V. Journal of the American Chemical Society, 1993 , vol. 115, # 8 p. 3080 - 3090]

Reactions of some alkynyl halides with Samarium (II) iodide

[Zhou, Zhihong; Larouche, Denis; Bennett, Sharon M. Tetrahedron, 1995 , vol. 51, # 43 p. 11623 - 11644]

Cyclizations during the Grignard Reactions of co-Bromoalkynes

[Crandall, Jack K.; Michaely, William J.; Collonges, Francois; Nelson, Deanna J.; Ayers, Timothy A.; Gajewski, Joseph J. Croatica Chemica Acta, 1996 , vol. 69, # 4 p. 1473 - 1490]

More Articles...