Thermal and electron-impact induced 1, 4 aryl migration from phosphorus to carbon

C Jongsma, R Lourens, F Bickelhaupt

Index: Jongsma,C. et al. Tetrahedron, 1976 , vol. 32, p. 121 - 124

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Citation Number: 8

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... 1,4-Migration of a phenyl group has been observed when 9-phenyl-10-t-butyl-9,10-dihydro-9 -phospha-anthracene 7 was subjected to pyrolysis at 500° or to electron-impact. The reaction is proposed to occur via 1-phosphabicyclo[2.2.1]heptyl-type species such as 10.