Reaction of ketone enolates with copper dichloride. Synthesis of 1, 4-diketones

Y Ito, T Konoike, T Saegusa

Index: Ito,Y. et al. Journal of the American Chemical Society, 1975 , vol. 97, p. 2912 - 2914

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Citation Number: 92

Abstract

(8) Control experiments established that the observed rotations were not artifacts of the work- up or analysis. Moreover, when an achiral electrolyte, tetra-n-butylammonium perchlorate, was employed, no selectivity could be detected. Optical purities were calculated assuming a molecular rotation of 29,700'at 546 mfi for optically pure 1.'(9) J.-Y. Sun, Ph. D. Thesis, University of North Carolina. 1967.(10) Currents were sampled at 200 msec following the ...