Tetrahedron Letters

Biomimetic entry to acyclic terpene synthesis a novel rearrangement of allyl ether catalyzed by organoaluminium reagents

Y Yamamura, K Umeyama, K Maruoka, H Yamamoto

Index: Yamamura, Yoshihiro; Umeyama, Kensuke; Maruoka, Keiji; Yamamoto, Hisashi Tetrahedron Letters, 1982 , vol. 23, # 18 p. 1933 - 1936

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Citation Number: 20

Abstract

Abstract The intramolecular prenyltransfer reaction is accomplished by the rearrangement of allyl ethers with (2, 6-di-tert-butyl-4-methylphenoxy) methylaluminum trifluoromethanesulfonate. The present method provides a simple and highly efficient synthesis of lavandulol.

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