Synthesis and NMR spectroscopy of stable isotope??labelled phenols and L??tyrosines

C Winkel, M Aarts, FR Van der Heide…

Index: Winkel, C.; Aarts, M. W. M. M.; Heide, F. R. van der; Buitenhuis, E. G.; Lugtenburg, J. Recueil des Travaux Chimiques des Pays-Bas, 1989 , vol. 108, # 4 p. 139 - 146

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Citation Number: 25

Abstract

Abstract The syntheses of (17 O) phenol from (17 O) water,(18 O) phenol from (18 O) water,(1-13 C)-phenol and (4-13 C) phenol from (2-13 C) acetone and (2-13 C) phenol and (3-13 C) phenol from (1-13 C)-acetone with high isotopic enrichment are described. The labelled phenols are converted into their corresponding L-tyrosines by the bacterium Erwinia herbicola. A full analysis of the 1 H and 13 C NMR spectra of phenol and L- ...