Journal of the American Chemical Society

Hydroxymethyl Derivatives of Phenols

IW Ruderman

Index: Ruderman Journal of the American Chemical Society, 1948 , vol. 70, p. 1662

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Abstract

(1946). good yield. This acid chloride was not isolated as such but converted to 2-nitr0-4- chlorophenylmer-captoacetic acid, which had previously been prepared by Pollack, Riesz and Kahane6 by the reaction of sodium chloroacetate with the sodium salt of 2-nitro-4- chlorophenylmercaptan. The new synthesis here reported seems to offer an easy approach to the mercaptoacetic acids. The ready reaction of ketene with 2-nitro-4- ...