Effect of precursor structures on arylcarbene processes in low-temperature matrices. Importance of topochemically controlled processes

H Tomioka, GW Griffin, K Nishiyama

Index: Tomioka,H. et al. Journal of the American Chemical Society, 1979 , vol. 101, p. 6009 - 6012

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Citation Number: 28

Abstract

Abstract: CH insertion selectivities of [PhCH:] generated from diverse sources, ie, PhCHNz and cis-and tmns-2, 3-diphenyloxiranes, in 2-propanol and 2.3-dimethylbutane matrices at- 196 OC showed considerable dependence on the structure of precursors, while liquid- phase experiments showed that insertion selectivities were essentially invariant regardless of source.[PhlC:] generated from Ph2CN2, tetraphenyloxirane. and 2, 2, 4, 4- ...

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