Photocontrolled Living Anionic Polymerization of Phosphorus??Bridged [1] Ferrocenophanes: A Route to Well??Defined Polyferrocenylphosphine (PFP) Homopolymers …

…, S Nagiah, CL Ho, WY Wong, I Manners

Index: Patra, Sanjib K.; Whittell, George R.; Nagiah, Simone; Ho, Cheuk-Lam; Wong, Wai-Yeung; Manners, Ian Chemistry - A European Journal, 2010 , vol. 16, # 10 p. 3240 - 3250

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Citation Number: 39

Abstract

Abstract Phosphorus-bridged strained [1] ferrocenophanes [Fe {(η-C 5 H 4) 2 P (CH 2 CMe 3)}](2) and [Fe {(η-C 5 H 4) 2 P (CH 2 SiMe 3)}](3) with neopentyl and (trimethylsilyl) methyl substituents on phosphorus, respectively, have been synthesized and characterized. Photocontrolled living anionic ring-opening polymerization (ROP) of the known phosphorus- bridged [1] ferrocenophane [Fe {(η-C 5 H 4) 2 P (CMe 3)}](1) and the new monomers 2 ...