Synthetic communications

New Application of Bromotrimethylsilane: Elaboration of Aldehydes/Ketones into Homologous α, β??Unsaturated Esters via β??Hydroxy Esters

SC Suri, JC Marcischak

Index: Suri, Suresh C.; Marcischak, Jacob C. Synthetic Communications, 2005 , vol. 35, # 3 p. 379 - 387

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Citation Number: 2

Abstract

The α,β??unsaturated ester is one of the important chemical functionalities that are encountered very commonly in organic synthesis. The standard method of introducing two carbon homologated α,β??unsaturated esters involves the Horner??Wadsworth??Emmons (HWE)1–7 View all references modification of the Wittig–olefination or the Peterson–olefination8–12 View all references of aldehydes/ketones. ... As part of synthetic project, the conversion of β??hydroxy ester to ...

Intramolecular Cyclization of 2, 7-or 2, 8-Bis-unsaturated Esters Mediated by (η2-Propene) Ti (Oi-Pr) 2. Facile Construction of Mono-and Bicyclic Skeletons with …

[Urabe; Suzuki; Sato Journal of the American Chemical Society, 1997 , vol. 119, # 42 p. 10014 - 10027]

Chameleon Reactivity of the Allene Bond of 4??Vinylidene??2??oxazolidinone: Novel Through??Space Conjugative Nucleophilic Addition of Electron??Rich Alkenes and …

[Morrill, Louis C.; Smith, Samuel M.; Slawin, Alexandra M. Z.; Smith, Andrew D. Journal of Organic Chemistry, 2014 , vol. 79, # 4 p. 1640 - 1655]

A new efficient decarboxylative reduction of γ-carbamoyloxy-α, β-unsaturated esters with lithium dialkylcuprate

[Ibuka, Toshiro; Chu, G.-Namg; Yoneda, Fumio Tetrahedron Letters, 1984 , vol. 25, # 30 p. 3247 - 3250]