The Journal of Organic Chemistry

A Novel Rearrangement of Epoxyalkyl Esters1

WV McConnell, WH Moore

Index: McConnell,W.V.; Moore,W.H. Journal of Organic Chemistry, 1963 , vol. 28, p. 822 - 827

Full Text: HTML

Citation Number: 5

Abstract

The unusual chemistry of 3, 4-epoxy-2, 2, 4-trimethyl-pentyl isobutyrate became apparent from the low values obtained from oxirane oxygen determinations and from gas chromatograms of the products formed when the epoxy ester was treated with acids. Vsing a modification of the procedure described by King, 4 the oxirane oxygen content of 3, 4-epoxy- 2, 2, 4-trimethylpentyl isobutyrate was indicated to be 2.2%. This is only 29% of the ...

Catalytic Decomposition of Carbonate Esters of 1, 3-Diols1, 2

[Searles,S. et al. Journal of the American Chemical Society, 1960 , vol. 82, p. 2928 - 2931]

Reaktionen mit Isobutyraldehyd, IV. 1??und 3??Isobuttersäureester des 2.2. 4??Trimethyl??pentandiols??(1.3)

[Schwenk,U.; Becker,A. Justus Liebigs Annalen der Chemie, 1972 , vol. 756, p. 162 - 169]

Butanones: Monoketones

[Julia,M.; Baillarge,M. Bulletin de la Societe Chimique de France, 1966 , p. 734 - 742]