The Journal of organic chemistry

Nitrosation of aryl and heteroaryltrifluoroborates with nitrosonium tetrafluoroborate

GA Molander, LN Cavalcanti

Index: Molander, Gary A.; Cavalcanti, Livia N. Journal of Organic Chemistry, 2012 , vol. 77, # 9 p. 4402 - 4413

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Citation Number: 31

Abstract

Organotrifluoroborates have emerged as an alternative to toxic and air-and moisture- sensitive organometallic species for the synthesis of functionalized aryl and heteroaryl compounds. It has been shown that the trifluoroborate moiety can be easily converted into a variety of different substituents in a late synthetic stage. In this paper, we disclose a mild, selective, and convenient method for the ipso-nitrosation of organotrifluoroborates using ...

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