The Nitration of Methyl α-Naphthoate and Related Compounds1

CF Koelsch, DO Hoffman

Index: Koelsch; Hoffman Journal of the American Chemical Society, 1943 , vol. 65, p. 989

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Citation Number: 2

Abstract

Because the nitration of methyl benzoate takes place so much more smoothly than does that of benzoic acid, 2 it was hoped that the nitration of methyl a-naphthoate might yield methyl 3, 8-dinitronaphthoate among the dinitration products. It has been found, however, that the main product of this reaction is methyl 4, 5-dinitronaphthoate, a substance which is also formed when methyl 5-nitronaphthoate is nitrated. The nitration of methyl 8- ...