The Journal of Organic Chemistry

Some new 3-substituted 3-hydroxyselenetanes and their loss of selenium

G Polson, DC Dittmer

Index: Polson, George; Dittmer, Donald C. Journal of Organic Chemistry, 1988 , vol. 53, # 4 p. 791 - 794

Full Text: HTML

Citation Number: 19

Abstract

3-Phenyl-, 3-@-methoxyphenyl)-, and 3-ethyl-3-hydroxyselenetane were prepared by treatment of 2-substituted 2-(chloromethy1) oxiranes with selenide ion at room temperature or lower. At elevated temperatures 2-substituted allyl alcohols were the major products. Treatment of 3-phenyl-3-hydroxyselenetane with base gave 2-phenyl-2-propenol, and attempts to prepare the benzoate and 3, 5-dinitrobenzoate of 3-phenyl-3- ...

Related Articles:

Regioselective Heck arylation of unsaturated alcohols by palladium catalysis in ionic liquid

[Mo, Jun; Xu, Lijin; Ruan, Jiwu; Liu, Shifang; Xiao, Jianliang Chemical Communications, 2006 , # 34 p. 3591 - 3593]

Novel conversion of epoxides to one carbon homologated allylic alcohols by dimethylsulfonium methylide

[Alcaraz, L.; Harnett, J. J.; Mioskowski, C.; Martel, J. P.; Gall, T. Le; et al. Tetrahedron Letters, 1994 , vol. 35, # 30 p. 5449 - 5452]

The influence of intramolecular dynamics on branching ratios in thermal rearrangements

[Newmann-Evans, Richard H.; Simon, Reyna J.; Carpenter, B. K. Journal of Organic Chemistry, 1990 , vol. 55, # 2 p. 695 - 711]

Palladium??Catalyzed Allylic Fluorination

[Hollingworth, Charlotte; Hazari, Amaruka; Hopkinson, Matthew N.; Tredwell, Matthew; Benedetto, Elena; Huiban, Mickael; Gee, Antony D.; Brown, John M.; Gouverneur, Veronique Angewandte Chemie - International Edition, 2011 , vol. 50, # 11 p. 2613 - 2617]

Rhodium promoted isomerisation of allylic alkoxides: a new method for enolate anion formation

[Gazzard, Lewis J.; Motherwell, William B.; Sandham, David A. Journal of the Chemical Society - Perkin Transactions 1, 1999 , # 8 p. 979 - 993]

More Articles...