Reactions of 2-Substituted Epichlorohydrins

…, IM Akhmedov, E Özgül, CG Kandemir

Index: Tanyeli; Demir; Akhmedov; Ozgul; Kandemir Synthetic Communications, 1996 , vol. 26, # 16 p. 2967 - 2980

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Citation Number: 9

Abstract

Abstract 2-Substituted epichlorohydrins have been synthesized by starting with 1, 2-dichloro acetone and various alkyl and aryl halides via dichlorohydrins followed by cyclization. The reactive 2-substituted epichlorohydrins were subjected to nucleophilic attacking of azide and cyanide ions to afford corresponding β-azido alcohols and α, β-unsaturated nitriles.

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