A convenient method for the aromatic amino-Claisen rearrangement of N-(1, 1-disubstituted-allyl) anilines

…, MA Lucas, JM Taylor, AD Ward, NM Williamson

Index: Cooper; Lucas; Taylor; Ward; Williamson Synthesis, 2001 , # 4 p. 621 - 625

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Citation Number: 26

Abstract

Abstract: N-(1, 1-Disubstituted-allyl) anilines are rearranged cleanly and in high yield to 2-(3, 3-disubstituted-allyl) anilines using a catalytic amount of p-toluenesulfonic acid in acetonitrile/water (10: 1). Key words: amino-Claisen, rearrangement, aromatic amines, alkenes, alkynes

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