Organic letters

A Facile Synthesis of 2-Methylquinolines via Pd-Catalyzed Aza-Wacker Oxidative Cyclization

Z Zhang, J Tan, Z Wang

Index: Zhang, Zuhui; Tan, Jiajing; Wang, Zhiyong Organic Letters, 2008 , vol. 10, # 2 p. 173 - 175

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Citation Number: 70

Abstract

Palladium-catalyzed processes play a vital role in the synthesis of heterocycles. 6 Recently, we reported a palladium-catalyzed intramolecular oxypalladation of phenol derivatives to synthesize 2-methylchromanones. 7 In light of the success of this Wacker-type oxidative cyclization, we turned our attention to a more challenging aza-Wacker oxidative cyclization. 8-9 Compared to the previous report, 7 the unusual 1,5-hydride alkyl to palladium migration is not observed in this aza- ...

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